How Are Alkenes Utilized in Modern Chemical Reactions and Applications?
In organic chemistry, alkenes are unsaturated hydrocarbons containing at least one carbon-carbon double bond. The simplest alkene is ethylene (C2H4), which is named by the International Union of Pure and Applied Chemistry (IUPAC), is the organic compounds produced on the largest scale industrially. The physical properties of alkenes depend on the molecular mass. The simple alkenes such as ethylene, propylene and butene are gases at room temperature, linear alkenes containing five to sixteen carbon atoms are liquid, and higher alkenes are usually waxy solids.
Alkenes are non-polar compounds, in which the only intermolecular force is the dispersion force, so the alkenes are not soluble in water but soluble in carbon tetrachloride and other organic solvents. The chemical property of alkenes is relatively stable, but more active than alkanes. Considering that the carbon-carbon double bonds in alkenes are stronger than the carbon-carbon single bonds in alkanes, most of the alkenes react by breaking the double bonds and forming two new single bonds.
Alkenes are known as the raw materials in petrochemical industry because they can be applied in a wide range of reactions including addition reaction, polymerization reaction and metal complexation reaction.
Applications
Addition reaction: Hydrogenation of alkenes produces the corresponding alkanes. The reaction is carried out at a temperature of 200 °C in the presence of a metal catalyst. Common industrial catalysts are platinum, nickel or palladium catalysts. In the presence of a suitable photosensitizer, the alkene can react with reactive oxygen species such as hydroxyl radicals, singlet oxygen or superoxide ion produced by the photosensitizer. A common example is the [4+2]-cyclicaddition of singlet oxygen to a diene to yield an endoperoxide.
Polymerization reaction: Polymerization of alkenes produces high-value polymers such as plastic polyethylene and polypropylene. Polymers derived from alkene monomers are generally referred to as polyolefins. A polymer from alpha-olefins is called a polyalphaolefin (PAO). Polymerization can proceed via free radical or ionic mechanisms, converting double bonds into single bonds and forming single bonds to link other monomers.
Metal complexation: Alkenes are important ligands in transition metal alkene complexes. Two carbon centers bonded to the metal are using C-C pi- and pi*-orbitals. Mono- and diolefins are often used as ligands in stable complexes. Cyclooctadiene and norbornadiene are popular chelating agents, and even ethylene is sometimes used as a ligand, for example in Zeise's salt. In addition, metal-alkene complexes are intermediates in many metal-catalyzed reactions, including hydrogenation, hydroformylation and polymerization.
Alkenes are non-polar compounds, in which the only intermolecular force is the dispersion force, so the alkenes are not soluble in water but soluble in carbon tetrachloride and other organic solvents. The chemical property of alkenes is relatively stable, but more active than alkanes. Considering that the carbon-carbon double bonds in alkenes are stronger than the carbon-carbon single bonds in alkanes, most of the alkenes react by breaking the double bonds and forming two new single bonds.
Alkenes are known as the raw materials in petrochemical industry because they can be applied in a wide range of reactions including addition reaction, polymerization reaction and metal complexation reaction.
Applications
Addition reaction: Hydrogenation of alkenes produces the corresponding alkanes. The reaction is carried out at a temperature of 200 °C in the presence of a metal catalyst. Common industrial catalysts are platinum, nickel or palladium catalysts. In the presence of a suitable photosensitizer, the alkene can react with reactive oxygen species such as hydroxyl radicals, singlet oxygen or superoxide ion produced by the photosensitizer. A common example is the [4+2]-cyclicaddition of singlet oxygen to a diene to yield an endoperoxide.
Polymerization reaction: Polymerization of alkenes produces high-value polymers such as plastic polyethylene and polypropylene. Polymers derived from alkene monomers are generally referred to as polyolefins. A polymer from alpha-olefins is called a polyalphaolefin (PAO). Polymerization can proceed via free radical or ionic mechanisms, converting double bonds into single bonds and forming single bonds to link other monomers.
Metal complexation: Alkenes are important ligands in transition metal alkene complexes. Two carbon centers bonded to the metal are using C-C pi- and pi*-orbitals. Mono- and diolefins are often used as ligands in stable complexes. Cyclooctadiene and norbornadiene are popular chelating agents, and even ethylene is sometimes used as a ligand, for example in Zeise's salt. In addition, metal-alkene complexes are intermediates in many metal-catalyzed reactions, including hydrogenation, hydroformylation and polymerization.
Tags: Addition Reaction, Alkenes, Catalysts, Ethylene, Metal Complexation, Organic Chemistry, Petrochemical Industry, Polymerization, Polyolefins, Unsaturated Hydrocarbons
Quelle:
Quelle:
What are conformations of molecules?
The molecule looks different in each confirmation, but the carbon frame work is the same.
What is a saturated hydrocarbon?
A hydrocarbon containing no multiple covalent bonds, with each carbon atom bonded to four other atoms.
What is an unsaturated hydrocarbon?
A hydrocarbon containing at least one multiple covalent bond.
What is a functional group?
A specific combination of atoms that behave as a unit in an organic molecule.
What is an alcohol?
An organic molecule that contains a hydroxyl group bonded to a saturated carbon.
What is a phenol?
An organic molecule in which a hydroxylgroup is bonded ro a benzene ring.
What is an ether?
An organic molecule containing an oxygen atom bonded to two carbon atoms.
What is an amine?
An organic molecule containing a nitrogen atom bonded to one or more saturated carbon atoms.
What is a carbonyl group?
A carbon atom double-bonded to an oxygen atom, found in ketones, aldehydes, amides, carboxylic acids, and esters.
What is a ketone?
An organic molecule conraining a carbonyl
group the carbon of which is bonded to two carbon atoms.
group the carbon of which is bonded to two carbon atoms.
What is an aldehyde?
An organic molecule containing a carbonyl group the carbon of which is bonded either to one carbon atom and one hydrogen atom or to two hydrogen atoms.
What is an amide?
An organic molecule containing a carbonyl group the carbon of which is bonded to a nitrogen atom.
What is a carboxylic acid?
An organic molecule containing a carbonyl group the carbon of which is bonded to a hydroxyl group.
What is an ester?
An organic molecule containing a carbonyl group the carbon of which is bonded to one carbon atom and one oxygen atom bonded to another carbon atom.
What is an addition polymer?
A polymer formed by the joining together of monomer units with no atoms lost as the polymer forms.
What is a condensation polymer?
A polymer formed by the joining together of monomer units accompanied by the loss of a small molecule, such as water.
Draw a benzene ring. What is its molecular formula? Why is it a "ring"?

Its molecular formula is C6H6 . It is a ring because it contains 3 double bonds that are able to "switch" between carbons.
What addition polymer is:

What is it used for and what is it recycling code?

What is it used for and what is it recycling code?
Polyethylene. Used in plastic bags;bottles.
Recycling Code 2 (HDPE) or 4 (LDPE).
Recycling Code 2 (HDPE) or 4 (LDPE).
What addition polymer is:

What is it used for and what is it recycling code?

What is it used for and what is it recycling code?
Polypropylene (PP). Used in carpets.
Recycling code 5(PP).
Recycling code 5(PP).
What addition polymer is:

What is it used for and what is it recycling code?

What is it used for and what is it recycling code?
Polystyrene (PS). Used in plastic utensils, insulation.
Recycling code 6(PS).
Recycling code 6(PS).
What addition polymer is:

What is it used for and what is it recycling code?

What is it used for and what is it recycling code?
Polyvinyl chloride (PVC). Use in pipes, shower curtain, tubing.
Recycling code 3(V).
Recycling code 3(V).
What addition polymer is:

What is it used for?

What is it used for?
Polyacrylonitrile (Orlon). Used in yarn and paint.
What addition polymer is:

What is it used for?

What is it used for?
Polymethyl methacrylate (Lucite, Plexiglass).
Used in Windows, bowling balls.
Used in Windows, bowling balls.
What condensation polymer is:

What are its uses?

What are its uses?
Nylon.
Used in carpeting and clothing.
Used in carpeting and clothing.
What condensation polymer is:

What are its uses?

What are its uses?
polyethylene terephthalate (Dacron, Mylar).
Used in clothing and plastic bottles.
Used in clothing and plastic bottles.
What condensation polymer is:

What are its uses?

What are its uses?
Melamine-formaldehyde resin. (Melmac, Formica)
Used in countertops and dishes.
Used in countertops and dishes.
What is a carbohydrate?
A biomolecule that contains only carbon, hydrogen, and oxygen atoms and is produced by plants through photosynthesis.
What is a D-sugar?
A carbohydrate in which the farthest chiral group from the top is facing right.
What is a L-sugar?
A carbohydrate in which the farthest chiral group from the top is facing left.

Kartensatzinfo:
Autor: mindyhausler
Oberthema: Biochemistry
Thema: Alkenes
Schule / Uni: Alfa Chemistry
Ort: New York
Veröffentlicht: 14.04.2025
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