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6
Oxidation of a double bond
1. KMnO
- mild conditions (vicinal diols)
- extreme conditions (carboxylic acids)
2. Ozonolysis
- mild conditions, reducing Zn/water environment (ketones/aldehydes)
- extreme conditions, oxidizing environment
3. NaBH or LiAlH
4. Peroxyacetic acids = CHCOH or MCPBA (epoxide formation)
5. Hydroboration (NaBH, peroxide)
- mild conditions (vicinal diols)
- extreme conditions (carboxylic acids)
2. Ozonolysis
- mild conditions, reducing Zn/water environment (ketones/aldehydes)
- extreme conditions, oxidizing environment
3. NaBH or LiAlH
4. Peroxyacetic acids = CHCOH or MCPBA (epoxide formation)
5. Hydroboration (NaBH, peroxide)
Tags: rxns
Source:
Source: